Characterization of a New Organic-Cation Cyclotetraphosphate: (1,4-HOC6H4NH3)4P4O12· 6H2O
Identifieur interne : 001A34 ( Main/Exploration ); précédent : 001A33; suivant : 001A35Characterization of a New Organic-Cation Cyclotetraphosphate: (1,4-HOC6H4NH3)4P4O12· 6H2O
Auteurs : E. H Soumhi ; I. Saadoune ; A. Driss [Tunisie] ; T. Jouini [Tunisie]Source :
- Journal of Solid State Chemistry [ 0022-4596 ] ; 1999.
English descriptors
- Teeft :
- Acta, Acta crystallogr, Angle values, Atomic arrangement, Cation, Condensed phosphates, Crystallogr, Cyclotetraphosphate, Deformation modes, Durif, Endothermic peaks, Hydrogen bonds, Inorganic sheets, Jouini, Local symmetry, Organic cation, Organic cations, Organic groups, Sect, Site group, Solid state inorg, Solid state ionics, Soumhi, Space group, Successive departure, Theoretical group analysis, Thermal analysis, Water molecules.
Abstract
Abstract: The tetra(para-phenolammonium)cyclotetraphosphate hexahydrate, (1,4-HOC6H4NH3)4P4O12· 6H2O (M=864.51 g mol−1), is monoclinicP21/cwith the unit cell parametersa=9.836(2) Å,b=8.591(1) Å,c:22.769(5) Å,β=95.41(2)°. The structure of this compound can be described as a succession of inorganic and organic sheets parallel to the (001) plane. The existence of the OH and NH3groups in positionparato the organic cation leads to the cohesion of the inorganic sheets, forming a three-dimensional network.The IR spectrum of (1,4-HOC6H4NH3)4P4O12· 6H2O is reported and discussed according to the theoretical group analysis. The IR data confirm the atomic arrangement within the structure. The coupled TG–DTA thermal study shows the successive departure of four and two water molecules, confirming the hydrated character of this cyclophosphate.
Url:
DOI: 10.1006/jssc.1999.8151
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 000492
- to stream Istex, to step Curation: 000492
- to stream Istex, to step Checkpoint: 000835
- to stream Main, to step Merge: 001A82
- to stream Main, to step Curation: 001A34
Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Characterization of a New Organic-Cation Cyclotetraphosphate: (1,4-HOC6H4NH3)4P4O12· 6H2O</title>
<author><name sortKey="Soumhi, E H" sort="Soumhi, E H" uniqKey="Soumhi E" first="E. H" last="Soumhi">E. H Soumhi</name>
</author>
<author><name sortKey="Saadoune, I" sort="Saadoune, I" uniqKey="Saadoune I" first="I" last="Saadoune">I. Saadoune</name>
</author>
<author><name sortKey="Driss, A" sort="Driss, A" uniqKey="Driss A" first="A" last="Driss">A. Driss</name>
</author>
<author><name sortKey="Jouini, T" sort="Jouini, T" uniqKey="Jouini T" first="T" last="Jouini">T. Jouini</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:EFE21ABEAE1894CA3C7B345E858615D68930026A</idno>
<date when="1999" year="1999">1999</date>
<idno type="doi">10.1006/jssc.1999.8151</idno>
<idno type="url">https://api.istex.fr/ark:/67375/6H6-LTT5MHT3-8/fulltext.pdf</idno>
<idno type="wicri:Area/Istex/Corpus">000492</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000492</idno>
<idno type="wicri:Area/Istex/Curation">000492</idno>
<idno type="wicri:Area/Istex/Checkpoint">000835</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000835</idno>
<idno type="wicri:doubleKey">0022-4596:1999:Soumhi E:characterization:of:a</idno>
<idno type="wicri:Area/Main/Merge">001A82</idno>
<idno type="wicri:Area/Main/Curation">001A34</idno>
<idno type="wicri:Area/Main/Exploration">001A34</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Characterization of a New Organic-Cation Cyclotetraphosphate: (1,4-HOC6H4NH3)4P4O12· 6H2O</title>
<author><name sortKey="Soumhi, E H" sort="Soumhi, E H" uniqKey="Soumhi E" first="E. H" last="Soumhi">E. H Soumhi</name>
<affiliation><wicri:noCountry code="subField">Morrocco</wicri:noCountry>
</affiliation>
</author>
<author><name sortKey="Saadoune, I" sort="Saadoune, I" uniqKey="Saadoune I" first="I" last="Saadoune">I. Saadoune</name>
<affiliation><wicri:noCountry code="subField">Morrocco</wicri:noCountry>
</affiliation>
</author>
<author><name sortKey="Driss, A" sort="Driss, A" uniqKey="Driss A" first="A" last="Driss">A. Driss</name>
<affiliation wicri:level="3"><country xml:lang="fr">Tunisie</country>
<wicri:regionArea>Faculté des Sciences de Tunis, Département de Chimie, Campus Universitaire, 1060, Tunis</wicri:regionArea>
<placeName><settlement type="city">Tunis</settlement>
<region nuts="2">Gouvernorat de Tunis</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Jouini, T" sort="Jouini, T" uniqKey="Jouini T" first="T" last="Jouini">T. Jouini</name>
<affiliation wicri:level="3"><country xml:lang="fr">Tunisie</country>
<wicri:regionArea>Faculté des Sciences de Tunis, Département de Chimie, Campus Universitaire, 1060, Tunis</wicri:regionArea>
<placeName><settlement type="city">Tunis</settlement>
<region nuts="2">Gouvernorat de Tunis</region>
</placeName>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j">Journal of Solid State Chemistry</title>
<title level="j" type="abbrev">YJSSC</title>
<idno type="ISSN">0022-4596</idno>
<imprint><publisher>ELSEVIER</publisher>
<date type="published" when="1999">1999</date>
<biblScope unit="volume">144</biblScope>
<biblScope unit="issue">2</biblScope>
<biblScope unit="page" from="318">318</biblScope>
<biblScope unit="page" to="324">324</biblScope>
</imprint>
<idno type="ISSN">0022-4596</idno>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">0022-4596</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="Teeft" xml:lang="en"><term>Acta</term>
<term>Acta crystallogr</term>
<term>Angle values</term>
<term>Atomic arrangement</term>
<term>Cation</term>
<term>Condensed phosphates</term>
<term>Crystallogr</term>
<term>Cyclotetraphosphate</term>
<term>Deformation modes</term>
<term>Durif</term>
<term>Endothermic peaks</term>
<term>Hydrogen bonds</term>
<term>Inorganic sheets</term>
<term>Jouini</term>
<term>Local symmetry</term>
<term>Organic cation</term>
<term>Organic cations</term>
<term>Organic groups</term>
<term>Sect</term>
<term>Site group</term>
<term>Solid state inorg</term>
<term>Solid state ionics</term>
<term>Soumhi</term>
<term>Space group</term>
<term>Successive departure</term>
<term>Theoretical group analysis</term>
<term>Thermal analysis</term>
<term>Water molecules</term>
</keywords>
</textClass>
<langUsage><language ident="en">en</language>
</langUsage>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Abstract: The tetra(para-phenolammonium)cyclotetraphosphate hexahydrate, (1,4-HOC6H4NH3)4P4O12· 6H2O (M=864.51 g mol−1), is monoclinicP21/cwith the unit cell parametersa=9.836(2) Å,b=8.591(1) Å,c:22.769(5) Å,β=95.41(2)°. The structure of this compound can be described as a succession of inorganic and organic sheets parallel to the (001) plane. The existence of the OH and NH3groups in positionparato the organic cation leads to the cohesion of the inorganic sheets, forming a three-dimensional network.The IR spectrum of (1,4-HOC6H4NH3)4P4O12· 6H2O is reported and discussed according to the theoretical group analysis. The IR data confirm the atomic arrangement within the structure. The coupled TG–DTA thermal study shows the successive departure of four and two water molecules, confirming the hydrated character of this cyclophosphate.</div>
</front>
</TEI>
<affiliations><list><country><li>Tunisie</li>
</country>
<region><li>Gouvernorat de Tunis</li>
</region>
<settlement><li>Tunis</li>
</settlement>
</list>
<tree><noCountry><name sortKey="Saadoune, I" sort="Saadoune, I" uniqKey="Saadoune I" first="I" last="Saadoune">I. Saadoune</name>
<name sortKey="Soumhi, E H" sort="Soumhi, E H" uniqKey="Soumhi E" first="E. H" last="Soumhi">E. H Soumhi</name>
</noCountry>
<country name="Tunisie"><region name="Gouvernorat de Tunis"><name sortKey="Driss, A" sort="Driss, A" uniqKey="Driss A" first="A" last="Driss">A. Driss</name>
</region>
<name sortKey="Jouini, T" sort="Jouini, T" uniqKey="Jouini T" first="T" last="Jouini">T. Jouini</name>
</country>
</tree>
</affiliations>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Sante/explor/H2N2V1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001A34 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 001A34 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Sante |area= H2N2V1 |flux= Main |étape= Exploration |type= RBID |clé= ISTEX:EFE21ABEAE1894CA3C7B345E858615D68930026A |texte= Characterization of a New Organic-Cation Cyclotetraphosphate: (1,4-HOC6H4NH3)4P4O12· 6H2O }}
This area was generated with Dilib version V0.6.33. |